Bis(μ-3-chlorobenzene-1,2-dicarboxylato-κ2 O 2:O 2)bis[diaqua(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)copper(II)]
نویسندگان
چکیده
In the centrosymmetric binuclear title compound, [Cu(2)(C(8)H(3)ClO(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(4)], the Cu(II) ion is six-coordinated by two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, two bridging O atoms from two 3-chloro-benzene-1,2-dicarboxyl-ate ligands and two water mol-ecules in a distorted octa-hedral geometry. The binuclear complex mol-ecules are linked together by inter-molecular O-H⋯O hydrogen bonds into a layer parallel to (100). The layers are connected by C-H⋯Cl hydrogen bonds. Intra-molecular O-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.5958 (16) Å] are also present.
منابع مشابه
Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)copper(II)]
The mol-ecule of the title binuclear copper(II) complex, [Cu(2)(C(14)H(8)O(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(2)], is bis-ected by a crystallographic twofold axis. Each Cu(II) atom is coordinated in a distorted octa-hedral geometry by three O atoms from two biphen-yl-2,2'-dicarboxyl-ate anions, one aqua O atom and two N atoms of a 4,4'-dimethyl-2,2'-bipyridine ligand. Intramolecular O-H⋯O hydroge...
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متن کاملBis(μ-2,2′-oxydibenzoato-κ4 O,O′:O′′,O′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc(II)] dihydrate
In the title compound, [Zn(2)(C(14)H(8)O(5))(2)(C(12)H(12)N(2))(2)]·2H(2)O, the Zn(II) atom exhibits a distorted octa-hedral coordination geometry, defined by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine ligand and four O atoms from two bridging 2,2'-oxydibenzoate ligands. The mol-ecule is a centrosymmetric dimer. π-π Stacking inter-actions are observed between the 4,4'-dimethyl-2,2'-bipy...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011