Bis(μ-3-chloro­benzene-1,2-dicarboxyl­ato-κ2 O 2:O 2)bis­[diaqua­(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)copper(II)]

نویسندگان

  • Fu-An Li
  • Fu Xu
  • Xiao-Ming Hu
چکیده

In the centrosymmetric binuclear title compound, [Cu(2)(C(8)H(3)ClO(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(4)], the Cu(II) ion is six-coordinated by two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, two bridging O atoms from two 3-chloro-benzene-1,2-dicarboxyl-ate ligands and two water mol-ecules in a distorted octa-hedral geometry. The binuclear complex mol-ecules are linked together by inter-molecular O-H⋯O hydrogen bonds into a layer parallel to (100). The layers are connected by C-H⋯Cl hydrogen bonds. Intra-molecular O-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.5958 (16) Å] are also present.

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011